期刊
CHEMICAL ENGINEERING JOURNAL
卷 392, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2019.123651
关键词
NiCo2S4@C nanosheets; Battery-type electrode; Asymmetric supercapacitor; Lithium-ion battery; Long cycling life; Phosphorization
资金
- Education department funding of Liaoning province [LJGD2019001]
- Guangxi Key Laboratory of Information Materials, Guilin University of Electronic Technology [191010-K]
- Guangxi Key Laboratory of Electrochemical Energy Materials [2019001]
Nickel cobalt sulfides are deemed as promising electrode materials for energy storage devices due to their rich redox active sites as well as superior conductivity. Herein, we report P-doped Ni-Co-S@C (PNCS@C) assemblies consisting of many nanosheets through facile one-step solvothermal route and a subsequent phosphorization process. The as-obtained product is utilized as electrode material for supercapacitor, which shows a specific capacity of 1026 C g(-1) at current density of 1 A g(-1). An asymmetric supercapacitor (ASC) delivers an energy density of 131.40 Wh kg(-1) at a power density of 1355.37 W kg(-1) . As anode material for lithium ion battery, it presents a discharge capacity of 2300.10 mAh g(-1) at 0.1 A g(-1). The superior electrochemical performance could be attributed to their unique spatial architectures and synergistic effect between composites.
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