期刊
CHEMCATCHEM
卷 12, 期 7, 页码 1944-1947出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201902332
关键词
molecular catalysis; formic acid; formaldehyde; catalytic hydrogenation; sustainable chemistry
Dialkoxymethanes are becoming increasingly important as fuel additives, formaldehyde surrogates, and chemical intermediates, but the effective synthesis remains challenging. Herein, the catalytic synthesis of dialkoxymethane products using a molecular catalyst is reported. The catalytic system, comprising the [Ru(triphos)(tmm)] in combination with the Lewis acid Al(OTf)(3), enables the direct synthesis of dialkoxymethane products with formic acid as C1 building block in high to excellent turnover numbers.
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