期刊
BIORESOURCE TECHNOLOGY
卷 293, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2019.122050
关键词
Microwave; FeCl3; Arundo donax L.; Second generation sugars; Levulinic acid
资金
- MIUR [20153T4REF]
The present work aimed to investigate and optimize the selective exploitation of hemicellulose and cellulose fractions of the energy crop Arundo donax L. (giant reed), to give xylose and levulinic acid, respectively. In order to improve the sustainability of this process, a microwave-assisted hydrolysis in the presence of FeCl3 was implemented using as substrate the raw biomass without any pretreatment process. The effects of the hydrolysis reaction conditions, such as temperature, reaction time, salt amount and biomass loading, on giant reed exploitation were investigated. In the first step, under the optimized conditions (150 degrees C, 2.5 min and 1.6 wt% FeCl3), the xylose yield reached 98.2 mol%. In the second step, under the best conditions (190 degrees C, 30 min and 2.4 wt% FeCl3), the levulinic acid yield was 57.6 mol%. This novel cascade approach ensured an extensive exploitation of giant reed polysaccharides working in the respect of Green Chemistry principles.
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