4.7 Article

Tracing the initial state of surface oxidation in black phosphorus

期刊

APPLIED SURFACE SCIENCE
卷 504, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.apsusc.2019.144341

关键词

Black phosphorus; Surface oxidation; Photoelectron spectroscopy

资金

  1. National Research Foundation (NRF) of Korea [2017R1A2B3011368, 2017R1A5A1014862, 2018K1A3A7A09027641]
  2. Future-leading Research Initiative of Yonsei University [2019-22-0079]
  3. U.S. Department of Energy, Office of Sciences [DE-AC02-05CH11231]
  4. National Research Foundation of Korea [2017R1A2B3011368, 2018K1A3A7A09027641] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Black phosphorus has emerged as a class of two-dimensional semiconductors, but its degradation caused by surface oxidation upon exposure to ambient conditions has been a serious issue. A key to understanding the mechanism of surface oxidation is the initial-state structure that has remained elusive. We study the initial state of surface oxidation in black phosphorus by low-temperature core-level photoelectron spectroscopy with the in situ dosage of O-2 in the ultrahigh-vacuum condition. Our high-resolution P 2p core-level spectra show two clearly distinct initial-state components of P atoms that have one and two neighboring O atoms, respectively. It is followed by the rapid growth of other higher binding-energy components originating from incomplete P2O5 bonded to black phosphorus with one or two less bonds to O atoms. The variation in the proportion of these components reveals the initial-state structure of dissociative adsorption and its evolution to the final form of phosphorus oxides.

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