期刊
APPLIED PHYSICS LETTERS
卷 116, 期 7, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/1.5133710
关键词
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资金
- DST Nanomission Grant [DST/NM/NS/2018/246]
- SERB Early Career Research Award [ECR/2018/001512]
- Department of Science and Technology, India [SR/NM/Z-07/2015]
- Advanced Photon Source, a U.S. Department of Energy Office of Science User Facility [DE-AC02-06CH11357]
High entropy oxides (HEOs) are a class of materials, containing equimolar portions of five or more transition metal and/or rare-earth elements. We report here about the layer-by-layer growth of HEO [(La0.2Pr0.2Nd0.2Sm0.2Eu0.2)NiO3] thin films on NdGaO3 substrates by pulsed laser deposition. The combined characterizations with in situ reflection high energy electron diffraction, atomic force microscopy, and x-ray diffraction affirm the single crystalline nature of the film with smooth surface morphology. The desired +3 oxidation of Ni has been confirmed by an element sensitive x-ray absorption spectroscopy measurement. Temperature dependent electrical transport measurements revealed a first order metal-insulator transition with the transition temperature very similar to the undoped NdNiO3. Since both these systems have a comparable tolerance factor, this work demonstrates that the electronic behaviors of A-site disordered perovskite-HEOs are primarily controlled by the average tolerance factor.
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