期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 258, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.apcatb.2019.117985
关键词
Active species; Cu-based catalysts; Heterogeneous fenton; Structure-performance relationship
资金
- National Science Foundation [21808057]
- Fundamental Research Funds for the Central Universities [222201718002]
- China Postdoctoral Science Foundation [2018M641941, 2019T120313]
- Innovation Scientists and Technicians Troop Construction Projects of Henan Province
Cu-based heterogeneous Fenton catalysts are promising for industrial wastewater treatment, nevertheless it remains a great challenge to understand the catalytic mechanism due to the difficulty in identifying the critical roles of coexisting Cu-0, Cu+ and Cu2+ species in the technical catalysts. In order to identify the catalytic roles of various copper species, core-shell Cu@SiO2 catalysts reduced at different reduction temperatures were studied for rhodamine B degradation. The Cu+ dominating catalyst, Cu@SiO2-R200, exhibited the highest degradation rate with more than 95% RhB (10 ppm) removal within 10 min. Combined with multiple techniques, including in situ spectroscopy, and density functional theory calculations, it can be concluded that Cu+ acts as the primary active species with the highest efficiency in activating the H2O2 to produce center dot OH and subsequently degrading the contaminants. In this work, the structure-performance relationship of Cu-based heterogeneous Fenton reaction was elucidated to inspire the rational design of high-performance heterogeneous catalysts.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据