期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 259, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.apcatb.2019.118087
关键词
Bi2MoO6; Thickness tuning; Nitrobenzene conversion; Photocatalytic reduction
资金
- National Natural Science Foundation of China [21673042, 21673043]
- Natural Science Foundation of Fujian Province of PR China [2017J01411]
High efficiency and selectivity is significant for photocatalytic organic transformation. In this work, the efficient photocatalytic reduction of nitrobenzene into aniline is achieved on non-noble metal thickness-tunable bismuth molybdate nanosheets prepared by the simple hydrothermal reaction. The photocatalytic activity of Bi2MoO6 strongly depends on the nanosheet thickness. The Bi2MoO6 monolayer displays remarkably enhanced photocatalytic activity for selective reduction of nitrobenzene than bilayer, multilayers and bulk Bi2MoO6 due to the unique properties of 2D materials with the large fraction of surface atoms and the ultrafast charge separation. The obtained conversion rate of 487.5 mu mol g(-1.)h(-1) ( > 95% conversion and > 99% selectivity within 60 min reaction) on Bi2MoO6 monolayers is 5 times higher than that of Bi2MoO6 bulk, far exceeding most of common photocatalysts up to date. This work provides a thickness dependent nanosheet concept in the design of newly highly efficient catalysts for the photocatalytic reduction conversion of nitroarenes to anilines.
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