期刊
APPLIED CATALYSIS A-GENERAL
卷 594, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.apcata.2020.117464
关键词
ZSM-5 zeolite; B-axis orientation; Hierarchical structure; Phosphorus modification; MTP reaction
资金
- National Natural Science Foundation of China [21908240]
- State Key Laboratory of Heavy Oil Processing [SKLOP201902001]
- Natural Science Foundation of Jiangsu Province
- China Postdoctoral Science Foundation [2018M642363]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
In this work, a b-axis oriented hierarchical ZSM-5 zeolite was prepared with glucose as an additive and further modified by phosphorus to improve the propylene selectivity and prolong the lifetime of the catalyst in a methanol to propylene (MTP) reaction. The physiochemical properties were characterized by XRD, low-temperature N-2 sorption, SEM, TEM, XPS, solid-state NMR, FTIR, and NH3-TPD analyses. The b-axis oriented ZSM-5 (Z5C) zeolite exhibited a microsized hexagonal lamellar structure with a thickness of approximately 220 nm. Analyzing the MTP reactions revealed that the newly prepared Z5-C catalyst exhibited a higher propylene selectivity of 53.01 % and a longer lifetime of 45 h compared to those of a conventional nanosized ZSM-5 catalyst (propylene selectivity of 43.97 % and lifetime of 10 h). In addition, the phosphorus modification remarkably increased the lifetime of the b-axis-oriented ZSM-5 catalyst to 79 h.
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