期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 59, 期 11, 页码 4396-4400出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202000323
关键词
acetylene; adsorption; gas separation; iron; metal-organic frameworks
资金
- Zhejiang Provincial Natural Science Foundation of China [LY20E020001]
- National Natural Science Foundation of China [51602301, 51672251]
- Welch Foundation [AX-1730]
- Fundamental Research Funds of Zhejiang Sci-Tech University [2019Q007]
The separation of C2H2/CO2 is particularly challenging owing to their similarities in physical properties and molecular sizes. Reported here is a mixed metal-organic framework (M ' MOF), [Fe(pyz)Ni(CN)(4)] (FeNi-M ' MOF, pyz=pyrazine), with multiple functional sites and compact one-dimensional channels of about 4.0 angstrom for C2H2/CO2 separation. This MOF shows not only a remarkable volumetric C2H2 uptake of 133 cm(3) cm(-3), but also an excellent C2H2/CO2 selectivity of 24 under ambient conditions, resulting in the second highest C2H2-capture amount of 4.54 mol L-1, thus outperforming most previous benchmark materials. The separation performance of this material is driven by pi-pi stacking and multiple intermolecular interactions between C2H2 molecules and the binding sites of FeNi-M ' MOF. This material can be facilely synthesized at room temperature and is water stable, highlighting FeNi-M ' MOF as a promising material for C2H2/CO2 separation.
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