期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 59, 期 23, 页码 8828-8832出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201913383
关键词
aggregation-induced emission; photochemical reactions; photodimerization; photomechanical luminescence; through-space conjugation
资金
- National Natural Science Foundation of China [21788102, 21673082]
- Natural Science Foundation of Guangdong Province [2019B030301003]
Transforming molecular motions into the macroscopic scale is a topic of great interest to nanoscience. The photomechanical effect is a promising strategy to achieve this goal. Herein, we report an intriguing photomechanical luminescence driven by the photodimerization of 2-phenylbenzo[b]thiophene 1,1-dioxide (P-BTO) in molecular crystals and elucidate the working mechanism and substituent effect through crystallographic analysis and theoretical calculations. Striking splitting, hopping, and bending mechanical behaviors accompanied by a significant blue fluorescence enhancement are observed for P-BTO crystals under UV light, which is attributed to the formation of photodimer 2P-BTO. Although 2P-BTO is poorly pi-conjugated because of the central cyclobutane ring, it exhibits prominent through-space conjugation and aggregation-induced emission (AIE), affording strong solid-state blue fluorescence at 415 nm with an excellent quantum yield of up to 96.2 %.
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