期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 59, 期 22, 页码 8623-8629出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201915988
关键词
borohydride; hydrogen; hydrogen storage; hydrolysis; regeneration
资金
- Australian Research Council's Discovery Projects funding scheme [DP170101773] Funding Source: Medline
- Foundation for Innovative Research Groups of the National Natural Science Foundation of China [No. NSFC51621001] Funding Source: Medline
- National Natural Science Foundation of China Projects [Nos. 51771075] Funding Source: Medline
- Natural Science Foundation of Guangdong Province [2016A030312011] Funding Source: Medline
- Guangdong Province Higher Vocational Colleges and Schools Pearl River Scholar Funded Scheme [2014] Funding Source: Medline
- Adaptable and Seamless Technology Transfer Program through Target-Driven R and D [No. 2018YFB15-02100] Funding Source: Medline
- Macau Science and Technology Development Fund (FDCT) [No.: 0062/2018/A2 and 118/2016/A3] Funding Source: Medline
Sodium borohydride (NaBH4) is among the most studied hydrogen storage materials because it is able to deliver high-purity H-2 at room temperature with controllable kinetics via hydrolysis; however, its regeneration from the hydrolytic product has been challenging. Now, a facile method is reported to regenerate NaBH4 with high yield and low costs. The hydrolytic product NaBO2 in aqueous solution reacts with CO2, forming Na2B4O7.10 H2O and Na2CO3, both of which are ball-milled with Mg under ambient conditions to form NaBH4 in high yield (close to 80 %). Compared with previous studies, this approach avoids expensive reducing agents such as MgH2, bypasses the energy-intensive dehydration procedure to remove water from Na2B4O7.10 H2O, and does not require high-pressure H-2 gas, therefore leading to much reduced costs. This method is expected to effectively close the loop of NaBH4 regeneration and hydrolysis, enabling a wide deployment of NaBH4 for hydrogen storage.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据