期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 59, 期 14, 页码 5706-5711出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201913079
关键词
aerogels; electrocatalysis; laser; ligand; noble metals
资金
- Alexander von Humboldt Foundation
- Humboldt Fellowship
- ERC AdG AEROCAT
- German Federal Ministry of Education of Research (BMBF) [03SF0451]
- German federal ministry of education and research (BMBF) (KontiKat) [FKZ 02P16K591]
- Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) [388390466-TRR 247]
- National Natural Science Foundation of China [51972237]
- Natural Science Foundation of Zhejiang Province [LY19E020008]
Noble metal aerogels (NMAs) are an emerging class of porous materials. Embracing nano-sized highly-active noble metals and porous structures, they display unprecedented performance in diverse electrocatalytic processes. However, various impurities, particularly organic ligands, are often involved in the synthesis and remain in the corresponding products, hindering the investigation of the intrinsic electrocatalytic properties of NMAs. Here, starting from laser-generated inorganic-salt-stabilized metal nanoparticles, various impurity-free NMAs (Au, Pd, and Au-Pd aerogels) were fabricated. In this light, we demonstrate not only the intrinsic electrocatalytic properties of NMAs, but also the prominent roles played by ligands in tuning electrocatalysis through modulating the electron density of catalysts. These findings may offer a new dimension to engineer and optimize the electrocatalytic performance for various NMAs and beyond.
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