期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 59, 期 5, 页码 2023-2027出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201912579
关键词
carboxylic acids; conjugation; covalent organic frameworks; post-synthetic modification; water treatment
资金
- King Abdulaziz City for Science and Technology (Center of Excellence for Nanomaterials and Clean Energy Applications)
- Office of Science of the US Department of Energy [DE-AC02-05CH11231]
- NIH [S10OD024998]
Three new post-synthetic modification reactions, namely amidation, esterification, and thioesterification, were demonstrated on a novel highly crystalline two-dimensional covalent organic framework (COF), COF-616, bearing pre-installed carboxyl groups. The strategy can be used to introduce a large variety of functional groups into COFs and the modifications can be carried out under mild reaction conditions, with high yields, and an easy work-up protocol. As a proof of concept, various chelating functionalities were successfully incorporated into COF-616 to yield a family of adsorbents for efficient removal of several contaminants in the water.
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