期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 59, 期 6, 页码 2246-2250出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201911961
关键词
allenes; asymmetric catalysis; carboetherification; palladium catalysis; Wacker reaction
资金
- Peking University Shenzhen Graduate School
- Shenzhen Bay Laboratory [21230011-Scripps]
- Nanyang Technological University
- GSK-EDB Trust Fund (2017 GSK-EDB Green and Sustainable Manufacturing Award)
- A*STAR Science and Engineering Research Council [AME IRG A1783c0010]
Palladium-catalyzed three-component carboetherification of cyclic alkenes proceeded to give trans adducts exclusively with excellent enantioselectivity through a Wacker-type pathway. The reaction is also applicable to other oxygen nucleophiles, such as water, phenols, and carboxylic acids, as well as some electron-poor aryl amines.
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