期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 362, 期 1, 页码 3-64出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201900864
关键词
green chemistry; multicomponent reactions; sulfur; synthetic applications; thiosulfonates
资金
- University of Antwerp (BOF)
- Research Foundation-Flanders (FWO)
- Francqui and Hercules Foundation
The synthetic strategies towards thiosulfonates (RSO2SR1) are comprehensively reviewed from their original discovery to recent advances. Incorporation of the green credentials of the synthetic procedures towards thiosulfonates allows one to judge the merits of the state of the art, beyond the typical yield of a product and availability of the reactants. As reactant for organic transformations, thiosulfonates are particularly interesting given their possibility to react with nucleophiles, electrophiles and radicals. This review aims to give researchers, not familiar with the field, a good understanding of the general applications of thiosulfonates, while not skipping the recent important advances. The related, but less explored, selenosulfonates (RSO2SeR1) are also covered.
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