期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 362, 期 3, 页码 659-666出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201901201
关键词
Organocatalysis; Selenium; Polymerization; High-throughput screening; trans-stilbenes
资金
- National Science Foundation [CHE-1902509]
- University of Pennsylvania
- FONDECYT/Postdoctorado [3160270]
The selenenate anion (RSeO-) is introduced as an active organocatalyst for the dehydrohalogen coupling of benzyl halides to form trans-stilbenes. It is shown that RSeO- is a more reactive catalyst than the previously reported sulfur analogues (sulfenate anion, RSO-) and selenolate anions (RSe-) in the aforementioned reaction. This catalytic system was also applied to the benzylic-chloromethyl-coupling polymerization (BCCP) of a bis-chloromethyl arene to form ppv (poly(p-phenylene vinylene))-type polymers with high yields, M-n (average molecular weight) up to 13,000 and D (dispersity) of 1.15.
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