期刊
ADVANCED FUNCTIONAL MATERIALS
卷 30, 期 10, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201909140
关键词
batteries; conductivity; electroceramics; electrolytes; LLTO
类别
资金
- Ford Motor Company Alliance Program
With the continued increase in Li-metal anode rate capability, there is an equally important need to develop high-rate cathode architectures for solid-state batteries. A proposed method of improving charge transport in the cathode is introducing a mixed electronic and ionic conductor (MEIC) which can eliminate the need for conductive additives that occlude electrolyte-electrode interfaces and lower the net additive required in the cathode. This study takes advantage of a reduced perovskite electrolyte, Li0.33La0.57TiO3 (LLTO), to act as a model MEIC. It is found that the ionic conductivity of reduced LLTO is comparable to oxidized LLTO (sigma(bulk) = 10(-3)-10(-4) S cm(-1), sigma(GB) = 10(-5)-10(-6) S cm(-1)) and the electronic conductivity is 1 mS cm(-1). The ionic transference numbers are 0.9995 and 0.0095 in the oxidized and reduced state, respectively. Furthermore, two methods for controlling the transference numbers are evaluated. It is found that the electronic conductivity cannot easily be controlled by changing O-2 overpressures, but increasing the ionic conductivity can be achieved by increasing grain size. This work identifies a possible class of MEIC materials that may improve rate capabilities of cathodes in solid-state architectures and motivate a deeper understanding of MEICs in the context of solid-state batteries.
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