期刊
ADVANCED FUNCTIONAL MATERIALS
卷 30, 期 17, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202000208
关键词
composite structures; iron carbodiimides; pyrolytic synthesis; sodium-ion batteries
类别
资金
- National Natural Science Foundation of China [51672165, 51702198]
- Postdoctoral Foundation of China [155660, 2016M592897XB]
- Natural Science Foundation of Shaanxi Province [2018JQ5107]
- National Key Research and Development Program of China [2017YFB0308303-03]
- Xi'an Key Laboratory of Green Manufacture of Ceramic Materials Foundation [2019220214SYS017CG039]
- Key Program for International S&T Cooperation Projects of Shaanxi Province
Iron carbodiimide (FeNCN) is a high-reactivity anode material for sodium-ion batteries. However, strict synthesis technology and poor electrochemical stability limit its application. FeNCN polyhedrons are prepared using a facile one-step pyrolysis process. In these polyhedrons, many anchor-like structures are in situ constructed with Fe-C bonds. These Fe-C bonds connect the FeNCN polyhedrons closely. The FeNCN polyhedrons with anchor-like structures exhibit good electrochemical stability, that is, high capacity retention of 79.9% (408 mAh g(-1)) at 0.5 A g(-1) after 300 cycles. Further analysis suggests that the Fe-C bond plays an important role to improve the structural stability of FeNCN polyhedrons. The anchor-like structures with Fe-C bonds can hold FeNCN polyhedrons closely when Na+ intercalates, avoiding structural breakage with obvious capacity loss. This work provides a novel synthesis technology of FeNCN and helps related researcher to deepen the understanding of this material, as well as provide inspirations as to improving the electrochemical stability of related materials.
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