4.8 Article

Light Gold: A Colloidal Approach Using Latex Templates

期刊

ADVANCED FUNCTIONAL MATERIALS
卷 30, 期 9, 页码 -

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201908458

关键词

composite materials; elemental gold; polymeric matrix; polystyrene; scaling behavior

资金

  1. ETH Zurich [ETH-43 17-1]
  2. SNSF [206021_183298]
  3. ScopeM/Swiss Federal Institute of Technology ETHZ
  4. Swiss National Science Foundation (SNF) [206021_183298] Funding Source: Swiss National Science Foundation (SNF)

向作者/读者索取更多资源

A new 18 karat light gold, composed of gold single crystals, amyloids, and a polymer latex matrix is developed. It is similar to a glassy plastic, yet lighter than aluminum and of use in watches, jewelry, radiation shielding, catalysis, and electronics. The material is prepared via a hydrogel precursor dried into an aerogel. Annealing of the polystyrene matrix under vacuum gives rise to a homogeneous template. The final apparent density and porosity of the material depend directly on the volumetric concentration of the starting solution used for hydrogel formation. After annealing, a homogeneous microstructure is obtained in which the shining gold single crystal platelets are evenly embedded in a polystyrene matrix. The material has a glass transition temperature of approximate to 105 degrees C which allows for annealing and molding above this temperature. A general scaling behavior is found for the Young's modulus of the material with the density. The Young's modulus of the material with a density of 1.7 g cm(-3) is approximate to 50 MPa. The density and stiffness, as well as the color, of the material can be tuned depending on the final application.

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