期刊
ACS NANO
卷 14, 期 2, 页码 2424-2435出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsnano.9b09839
关键词
antiferromagnetic semiconductors; quasi-2D materials; Raman spectroscopy; thermal conductivity; spintronics
类别
资金
- Spins and Heat in Nanoscale Electronic Systems (SHINES), an Energy Frontier Research Center - U.S. Department of Energy, Office of Science, Basic Energy Sciences (BES) [SC0012670]
- National Science Foundation [ACI-1548S62, TG-DMR130081]
We report results of investigation of the phonon and thermal properties of the exfoliated films of layered single crystals of antiferromagnetic FePS3 and MnPS3 semiconductors. Raman spectroscopy was conducted using three different excitation lasers with wavelengths of 325 nm (UV), 488 nm (blue), and 633 nm (red). UV-Raman spectroscopy reveals spectral features which are not detectable via visible Raman light scattering. The thermal conductivity of FePS3 and MnPS3 thin films was measured by two different techniques: the steady-state Raman optothermal and transient time-resolved magneto-optical Kerr effect. The Raman optothermal measurements provided the orientation-average thermal conductivity of FePS3 to be 1.35 +/- 0.32 W m(-1) K-1 at room temperature. The transient measurements revealed that the through-plane and in-plane thermal conductivity of FePS3 are 0.85 +/- 0.15 and 2.7 +/- 0.3 W m(-1) K-1, respectively. The films of MnPS3 have higher thermal conductivity of 1.1 +/- 0.2 W m(-1) K-1 through-plane and 6.3 +/- 1.7 W m(-1) K-1 in-plane. The data obtained by the two techniques are in agreement and reveal strong thermal anisotropy of the films and the dominance of phonon contribution to heat conduction. The obtained results are important for the interpretation of electric switching experiments with antiferromagnetic materials as well as for the proposed applications of the antiferromagnetic semiconductors in spintronic devices.
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