期刊
ACS NANO
卷 14, 期 1, 页码 899-906出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsnano.9b08186
关键词
two-dimensional materials; transition-metal dichalcogenide alloy; phase engineering phase transition; chemical vapor deposition
类别
资金
- Whiting School of Engineering, Johns Hopkins University, USA
- World Premier International (WPI) Research Center Initiative for Atoms, Molecules and Materials, MEXT, Japan
Two-dimensional (2D) transition-metal dichalcogenides (TMDs) are prospective materials for quantum devices owing to their inherent 2D confinements. They also provide a platform to realize even lower-dimensional in-plane electron confinement, for example, OD quantum dots, for exotic physical properties. However, fabrication of such laterally confined monolayer (1L) nanostructure in 1L crystals remains challenging. Here we report the realization of 1L ReS2 quantum dots epitaxially inlaid in 1L MoS2 by a two-step chemical vapor deposition method combining with plasma treatment. The lateral lattice mismatch between ReS2 and MoS2 leads to size-dependent crystal structure evolution and in-plane straining of the 1L ReS2 quantum dots. Optical spectroscopies reveal the abnormal charge transfer between the 1L ReS2 quantum dots and the MoS2 matrix, resulting from electron trapping in the 1L ReS2 quantum dots. This study may shed light on the development of in-plane quantum-confined devices in 2D materials for potential applications in quantum information.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据