期刊
ACS APPLIED MATERIALS & INTERFACES
卷 12, 期 1, 页码 1867-1876出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.9b17623
关键词
photocatalysis; Bi2MoO6; metallic Bi; molecular oxygen activation; sodium pentachlorophenate
资金
- National Natural Science Foundation of China [51572101, 21607047, 51872107]
- Natural Science Foundation of Hubei Province [2016CFB193]
- Fundamental Research Funds for the Central Universities [2662015QD047, 2662016PY088, 2662015QD011, 2015PY120, 2015PY047]
Construction of the semimetal/semiconductor composite interface is widely used to promote the O-2 molecule adsorption and charge transfer for boosting solar-driven molecular oxygen activation (MOA). Herein, a Bi@Bi2MoO6 heterostructure is fabricated via a two-step wet chemical method as a typical photocatalyst to investigate the underlying mechanism of Bi-coordinated facet-dependent MOA under visible-light illumination. Density functional theory and systematical characterization methods reveal the distinct charge transfer and O-2 activation processes on the surface of Bi nanoparticle-deposited Bi2MoO6 nanosheets with different facets exposed. By virtue of a particular and efficient [Bi2O2](2+) -> Bi -> MoO42- interfacial charge-transfer channel, Bi deposited on the (001) facet of Bi2MoO6 can observably intensify MOA, thereby giving birth to more generation of reactive oxygen species and endowing the Bi@Bi2MoO6 with excellent photocatalytic performance in sodium pentachlorophenate (NaPCP) removal. The decomposition pathway of NaPCP is also proposed based on the intermediate determination and mineralization analysis. This work provides deep insights into the mechanism of facet-dependent MOA over a semimetal-semiconductor system and also sheds light on designing effective molecular oxygen-activated interface for environmental remediation.
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