期刊
ACS APPLIED MATERIALS & INTERFACES
卷 12, 期 6, 页码 7198-7205出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.9b19867
关键词
self-assembly; core-shell structure; recyclable nanocatalyst; MOFs; selective hydrogenation
资金
- National Natural Science Foundation of China [21601135, 21875117]
Controlling and manipulating the self-assembly technology at the nanoscale has become a powerful strategy for improving chemical processes and further developing the conception of atom efficiency. Herein, an unexpected core-shell structured Gd2O3@Pt@ZIF-8 nano-reactor has been fabricated using the self-assembly strategy in which the firm Gd2O3 nanosupport anchored the highly active Pt nanoparticle coated porous zeolitic imidazolate framework (ZIF-8). The well-designed Gd2O3@Pt@ZIF-8 structure shows good performance in selective hydrogenation of aldehyde-, keto-, and nitro-compounds with full conversion (>99.9%) and superior selectivity (>95%). It showed the channel sieving effect of the ZIF-8 channels toward enhancing the catalytic selectivity. After being recycled eight times, their activity remains unchanged and their core-shell structure is kept intact. So, the outer ZIF-8 membranes not only prevent Pt nanoparticles from agglomeration and slipping during a catalytic reaction but also maintain the original activity and long-term stability compared to the Gd2O3@Pt catalyst. The self-assembly strategy demonstrated here will allow the development of other highly active, stable, and selective catalysts for important but challenging transformations.
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