期刊
NATURE CATALYSIS
卷 2, 期 11, 页码 955-970出版社
NATURE PUBLISHING GROUP
DOI: 10.1038/s41929-019-0364-x
关键词
-
资金
- Shell Global Solutions
- Netherlands Association for Scientific Research
- Companhia Brasileira de Metalurgia e Mineracao
- European Research Council, EU FP7 ERC Advanced Grant [338846]
- European Research Council (ERC) [338846] Funding Source: European Research Council (ERC)
Metal nanoparticles stabilized on a support material catalyse many major industrial reactions. Metal-support interactions in these nanomaterials can have a substantial influence on the catalysis, making metal-support interaction modulation one of the few tools able to enhance catalytic performance. This topic has received much attention in recent years, however, a systematic rationalization of the field is lacking due to the great diversity in catalysts, reactions and modification strategies. In this review, we cover and categorize the recent progress in metal-support interaction tuning strategies to enhance catalytic performance for various reactions. Furthermore, we quantify the productivity enhancements resulting from metal-support interaction control that have been achieved in C-1 chemistry in recent years. Our analysis shows that up to fifteen-fold productivity enhancement has been achieved, and that metal-support interaction is most impactful for metal nanoparticles smaller than four nanometres. These findings demonstrate the importance of metal-support interaction to improve performance in catalysis.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据