期刊
MOLECULAR CATALYSIS
卷 475, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.mcat.2019.110483
关键词
Chromene derivatives; HMF synthesis; Porous organic polymers; Sulfonation; Surface acidic and basic sites
资金
- UGC, New Delhi
- DST, New Delhi
- CSIR, New Delhi [09/080(0881)/2013-EMR-I]
- Department of Science and Technology (DST), New Delhi through DST-SERB core research grant [CRG/2018/000230]
Functionalized porous organic polymers are very demanding and promising material in heterogeneous catalysis due to their convenience in synthesis and versatility in framework composition. Further, owing to the tunable porosity, high specific surface area, ease of functionalization and chemical stability, this class of porous polymers have huge potential to be employed both as catalysis and catalyst support. Herein, we report N-rich triazinethiophene based microporous polymer TrzDBTH through the Friedel-Craft alkylation reaction of tripodal building block 2,4,6-tris[4-(bromomethyl)phenyl]-1,3,5-triazine with dibenzothiophene (DBTH) and used it as a heterogeneous base catalyst for one-pot synthesis of biologically important chromene derivatives. Further, sulfonation to this TrzDBTH material yielded sulfonated hyper-crosslinked porous polymer namely STrzDBTH, which can be used as solid acid catalyst for the synthesis of valuable chemical intermediate 5-hydroxymethylfurfural (HMF) from different biomass derived carbohydrates. As a base catalyst, TrzDBTH provides chromene yields from 88 to 93% and its sulfonated derivative STrzDBTH provides the HMF yields from 57 to 97% for different carbohydrate substrates. Both the materials displayed high recycling efficiencies for several catalytic cycles. Thus, these triazine-thiophene based porous organic polymers offer very economical, scalable and recyclable routes for the synthesis chromene derivatives and HMF.
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