期刊
MATERIALS & DESIGN
卷 180, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.matdes.2019.107908
关键词
Dealloying; Porous materials; Ordered FeCo; Microstructure; Double gyroid; Nano ligament
资金
- Ministry of Education, Culture, Sports, Science and Technology (MEXT, Japan) [18H05452]
- International Collaboration Center Institute for Materials Research (ICC-IMR, Tohoku University)
- Grants-in-Aid for Scientific Research [18H05452] Funding Source: KAKEN
Liquid metal dealloying is a promising technique for synthesizing non-noble porous materials by preventing oxidation in a metallic melt. This method considers the heats of mixing between precursor elements and a melt element to design miscible and immiscible elements for a precursor. In this study, Ni and Co were selected as the miscible elements in an Mg melt as constituents of (FeCo) 100 ,Ni x precursor alloys to understand the complex mechanisms of their dissolution behavior. Dissolution of the second miscible element, Co, was governed by the composition of the Mg melt, because the characteristics of the melt changed in the presence of a high amount of dissolved Ni and its convection. The synthesized FeCo ligaments showed morphology variations depending on the dealloying temperature: the ligaments become more elongated along the dealloying direction at higher temperatures. A double-gyroid-like porous structure with a narrow liquid channel, produced from the (FeCo)(70)Ni-30 precursor, exhibited the highest specific surface area at all processing temperatures from 600 degrees C to 800 degrees C. This structure differed completely from that of the typical porous Fe80Cr20 alloy produced under the same liquid metal dealloying conditions. Elongation resulted from time-dependent directional coarsening behavior that was affected by the composition of the Mg melt. (C) 2019 The Authors. Published by Elsevier Ltd.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据