期刊
MATERIALS RESEARCH EXPRESS
卷 6, 期 12, 页码 -出版社
IOP PUBLISHING LTD
DOI: 10.1088/2053-1591/ab4a5f
关键词
phase change materials; cellulose nanofibers; microcapsule; thermoregulation
A series of microencapsulated phase change materials (microPCMs) are synthesized by encapsulating 1-dodecanol into cellulose nanofibers (CNFs) modified melamine-formaldehyde (MF) resin through in situ polymerization. The chemical structure and crystallography of the microcapsules are characterized by Fourier-transform infrared spectroscopy (FT-IR) and x-ray diffraction (XRD). Scanning electronic microscopy (SEM) images show that the obtained microcapsules are regularly spherical with smooth surface and an average diameter about 1 similar to 3 mu m. The cracking ratio test indicates that the addition of CNFs largely enhances the mechanical strength of the microcapsules, and the CNFs/MF-microPCMs (with 3.4 wt% CNFs) have a phase change enthalpy of 100.4 J g(-1). Furthermore, the simulation result demonstrates that the indoor temperature modulation ability of CNFs/MF-microPCMs model house is 4.2 degrees C, which is more than that of model house without microPCMs under room temperature. These results indicate that CNFs/MF-microPCMs are potential candidates for thermoregulating applications.
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