Construction of Silver Quantum Dot Immobilized Zn-MOF-8 Composite for Electrochemical Sensing of 2,4-Dinitrotoluene

In the present study, we report a highly effective electrochemical sensor for detecting 2,4-dinitrotoluene (2,4-DNT). The amperometric determination of 2,4-DNT was carried out using a gold electrode modified with zinc-metal organic framework-8 and silver quantum dot (Zn-MOF-8@AgQDs) composite. The synthesized nanomaterials were characterized by using transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR) and X-ray powder diffraction (XRD). The synthesized nanocomposite proved to be efficient in electro-catalysis thereby reducing the 2,4-DNT. The unique combination present in Zn-MOF-8@AgQDs composite offered an excellent conductivity and large surface area enabling the fabrication of a highly sensitive (-0.238 mu A mu M-1 cm(-2)), selective, rapid and stable 2,4-DNT sensor. The dynamic linear range and limit of detection (LOD) was about 0.0002 mu M to 0.9 mu M and 0.041 mu M, respectively. A 2,4-DNT reduction was also observed during the linear sweep voltammetry (LSV) experiments with reduction peaks at -0.49 V and -0.68 V. This is an unprecedented report with metal organic framework (MOF) composite for sensing 2,4-DNT. In addition, the presence of other species such as thiourea, urea, ammonia, glucose, and ascorbic acid displayed no interference in the modified electrode suggesting its practicability in various environmental applications.