4.8 Article

Room temperature synthesis of stable single silica-coated CsPbBr3 quantum dots combining tunable red emission of Ag-In-Zn-S for High-CRI white light-emitting diodes

期刊

NANO ENERGY
卷 67, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.nanoen.2019.104279

关键词

CsPbBr3 QDs; Stability; Ag-In-Zn-S QDs; WLEDs

资金

  1. National Natural Science Foundation of China [11974063, 61574024]
  2. Defense Industrial Technology Development Program [JCKY2017110C0654]
  3. Key Program Science Foundation of Natural Science Foundation of Chongqing [cstc2017jcyjBX0054]
  4. Graduate Scientific Research and Innovation Foundation of Chongqing [CYB19061]

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White light emitting diodes (WLEDs) based on all-inorganic halide (CsPbX3, X = Cl, Br and I) perovskite quantum dots (QDs) have attracted broad attention due to their high brightness. However, their poor stability and anionexchange reaction when utilized together are still the main challenges that impede their applications. Herein, a one-step in situ method under room temperature in air is proposed to synthesize CsPbBr3 QDs coated with SiO2 (CsPbBr3@SiO2), where the whole process takes only 20 s. The as-prepared CsPbBr3@SiO2 QDs samples present an enhanced stability in the thermal and polar-solvent environment, maintaining its high photoluminescence quantum yield (PLQY-75%). Thereby WLEDs are constructed by combining CsPbBr3@SiO2 with red Ag-In-Zn-S QDs on InGaN blue chip, achieving a high color rendering index (CRI) of 91, a correlated color temperature (CCT) of 3689 K and a power efficiency of 40.6 lm(-)(1).

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