期刊
JOURNAL OF ENERGY CHEMISTRY
卷 51, 期 -, 页码 418-424出版社
ELSEVIER
DOI: 10.1016/j.jechem.2019.11.006
关键词
Carbon dioxide; Electrochemical conversion; Molten carbonates; Carbon; Supercapacitor
资金
- National Natural Science Foundation of China [21673162]
- International Science & Technology Cooperation Program of China [2015DFA90750]
The electrochemical reduction of CO2 to capacitive carbon in molten Li2CO3-Na2CO3-K2CO3 is an effective strategy for capturing and utilizing CO2. This paper reports the effects of the cell voltages and operating temperatures (450-650 degrees C) of the molten salt electrolysis on the capacitive performance of electrolytic carbon. The electrolytic carbon delivers excellent specific capacitance when the cell voltage is 4.5 V and the temperature of molten salt is 450 degrees C. The carbon obtained at 450 degrees C and under 4.5 V delivers a specific capacitance of 550 F g(-1) at 0.2 A g(-1) in 1 M aqueous H2SO4, and the capacity retention rate is 73% after 10 0 0 0 cycles. The specific capacitance of the electrolytic carbon increases as the electrolysis temperature decreases, and the optimal cell voltage is 4.5 V. (c) 2019 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
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