期刊
SCIENTIFIC REPORTS
卷 9, 期 -, 页码 -出版社
NATURE PORTFOLIO
DOI: 10.1038/s41598-019-48696-y
关键词
-
资金
- National Natural Science Foundation of China [21601038, 21771043]
- Guangxi Natural Science Foundation [2016GXNSFAA380085]
Four complexes, namely, [Ln(2)(L-2)(2)(NO3)(4)]. 2CH(3)OH (Ln = Tb (1), Dy (2), Ho (3), Er (4), and L2 = (E)-2-methoxy-6-(((pyridin-2-ylmethyl) imino) methyl) phenol), were obtained by reacting (E)-2-((3-methoxy-2-oxidobenzylidene) amino) ethanesulfonate (L1), Ln(NO3)(3)center dot 6H(2)O, and 2-aminomethylpyridine at room temperature under solvothermal conditions in methanol for 12 h. The new Schiff base L2 was generated in situ based on the organic ligand L1 and 2-aminomethylpyridine through Schiff base exchange reaction by using lanthanide salts as inductor. A combination of crystallography and mass spectrometry was performed to track the exchange reaction, and the underlying mechanism accompanied by the complex assembly process was clearly presented. The multistep formation mechanism of the above dinuclear complex was also proposed, i.e., [L1] -> Dy[L1]/[L2] -> Dy[L2] -> Dy[L2](2) -> Dy-2[L2](2). Luminescence test of 1 showed that it had extremely high selectivity to dichloromethane (CH2Cl2). Therefore, we established a quick, simple, and efficient method of detecting CH2Cl2 that enabled strong-luminescence observation with the naked eye. Tests for small amounts of CH2Cl2 in water further indicated the potential of 1 as a test strip for CH2Cl2 fluorescence detection in water samples. Alternating-current magnetic susceptibility studies indicated the field-induced single-molecule magnet behavior of 2.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据