期刊
ACS CATALYSIS
卷 9, 期 12, 页码 11125-11129出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.9b03476
关键词
manganese; cobalt; oxidation; C-C bond activation; heterocycles
资金
- Federal Ministry of Education and Research (BMBF)
- State of Mecklenburg-Vorpommern
- Fonds der Chemischen Industrie [103231]
Catalytic methods for the site-selective scission of C(sp(3))-C(sp(3)) bonds remain scarcely explored in contrast to the vast literature on C-C coupling. In view of this, we report a means of oxidative C-C single-bond cleavage in morpholines, made possible by a synergy between cobalt and manganese catalysts using air as a benign oxidant. We demonstrate the synthetic utility of this system with the late-stage oxidative cleavage of Linezolid.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据