4.1 Article

Synthesis and Structures of Dinuclear Aluminum Complexes Based on Bis(β-diketiminate) Ligands

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出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.201900193

关键词

Aluminum alkyl compounds; Aluminum; Bis(beta-diketiminate); Dinuclear aluminum complexes; Group 13; Synergy

资金

  1. Fonds der Chemischen Industrie
  2. Deutsche Forschungsgemeinschaft (DFG) [KR4782/2-1, KR4782/3-1]
  3. University of Regensburg
  4. Friedrich Schiller University Jena
  5. Stiftung Stipendien-Fonds des Verbands der Chemischen Industrie

向作者/读者索取更多资源

A series of ten dinuclear aluminum alkyl complexes based on rigid, semirigid, and flexible bis(beta-diketiminate) ligands (NacNac) has been obtained from the reaction of trimethylaluminum and the corresponding bis(beta-diketimine)s. All compounds were fully characterized using NMR and IR spectroscopy and elemental analysis. The molecular structures of five compounds have been investigated by means of single-crystal X-ray diffraction analysis.

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