期刊
TETRAHEDRON LETTERS
卷 60, 期 48, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2019.151284
关键词
Iodine; Visible light; Radical reaction; Lactone
资金
- Kato Memorial Bioscience foundation
- Gifu Pharmaceutical University
This manuscript describes the reaction of dienes with carbonyls in the presence of molecular iodine under visible light irradiation to furnish the corresponding butyrolactones with complete site selectivity. The reaction proceeds via site selective sequential addition of iodine radical, which is generated from molecular iodine under visible light irradiation, to dienes to form a reactive intermediate, followed by substitution and cyclization. A variety of dienes and carbonyls are well tolerated under the reaction conditions. This transformation constitutes the first iodine radical-mediated intermolecular lactonization reaction of dienes. (C) 2019 Elsevier Ltd. All rights reserved.
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