期刊
SYNTHESIS-STUTTGART
卷 52, 期 5, 页码 775-780出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0039-1690758
关键词
hydroarylation; diazo compounds; arylacetates; palladium catalysis; cross coupling; phosphonates
资金
- Russian Science Foundation [19-13-00223]
- Russian Science Foundation [19-13-00223] Funding Source: Russian Science Foundation
A simple synthetic procedure for the Pd-catalyzed hydroarylation of diazoacetic ester has been previously developed in our laboratory. Now we have applied this methodology for hydroarylation of alpha-diazocarboxylates/alpha-diazophosphonates. Diazo compounds reacted with aryl iodides and formic acid to afford diarylated esters or phosphonates in yields up to 71%.
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