期刊
SOLID STATE IONICS
卷 338, 期 -, 页码 103-112出版社
ELSEVIER
DOI: 10.1016/j.ssi.2019.05.012
关键词
PEMFC; ATRP; Phosphonated polysulfone; Sulfonated polysulfone
资金
- National Natural Science Foundation of China [21376147, 21573143, 21706156]
- National Key Research and Development Program of China [2017YFB0102900]
- Shanghai Pujiang Program [17PJDO16]
Polysulfone-g-(phosphonated polystyrene) (PPSF) is synthesized by grafting of poly(phosphonated polystyrene) to polysulfone (PSF) backbone via controlled atom-transfer radical polymerization (ATRP). And its comprehensive performances are improved by compositing with sulfonated polysulfone (SPSF). The best comprehensive performances are achieved in the composite membrane consisting of 80 wt% PPSF and 20 wt% SPSF (P80S20). The maximum proton conductivity reaches 17.23 mS cm(-1) at 95 degrees C and 90% RH, which is 3.3 times as high as the pristine PPSF at 5.22 mS cm(-1). In addition, the composite membrane exhibits favorable thermal stability, compromised water uptake and swelling ratio, significantly improved mechanical strength. Moreover, the methanol permeability is reduced from 5.74 x 10(-8) cm(2) s(-1) for PPSF to 0.96 x 10(-8) cm(2) s(-1) for P80S20.
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