期刊
SENSORS AND ACTUATORS B-CHEMICAL
卷 298, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2019.126860
关键词
Hierarchical; Co3O4@CuO; Core-shell structure; Carbon cloth; Non-enzymatic biosensor; Glucose sensor
资金
- Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy [DE-AC02-05CH11231]
- China Scholarship Council
- National Basic Research Program of China [2015CB057205]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT13017]
- National Science Foundation of China [51775218]
A hierarchical core-shell Co3O4/CuO nanorod array (NRA) anchored on flexible carbon cloth (CC) has been fabricated through a stepwise process consisting of magnetron sputtering of Cu, its anodic oxidation, and chemical bath deposition of Co3O4. The structure, composition and morphology of the synthesized Co3O4/CuO NRA on CC were characterized by X-ray diffraction (XRD), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The glucose sensing performance of the Co3O4/CuO NRA on CC electrode was investigated by cyclic voltammetry and chronoamperometry. The sensor exhibited a high sensitivity of 5405 mu A mM(-1) cm(-2) with a fast response time (t(90) = 1.9 s) and a low detection limit of 0.38 mu M. The electrode also showed outstanding selectivity toward various interferences. These results indicate that the Co3O4/CuO nanocomposites may be promising electrode materials for electrochemical biosensing.
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