期刊
POLYMERS FOR ADVANCED TECHNOLOGIES
卷 31, 期 3, 页码 527-535出版社
WILEY
DOI: 10.1002/pat.4793
关键词
carbon fiber; halloysite nanotubes; interface; polymer composite; surface modification
资金
- Natural Science Foundation of China [21806070]
- Natural Science Foundation of Shandong Province, China [ZR2018PB017]
In the present research, a multifunctional hierarchical reinforcement was prepared by chemical modification of carbon fibers (CFs) with halloysite nanotubes (HNTs) by the bridging diethylenetriaminepentaacetic acid (DTPA) for improving interfacial microstructures and properties of composites. Surface structures and groups of modified HNTs and CFs were characterized systematically. The uniform distributions of the introduced DTPA and HNTs helped to increase fiber polarity, surface energy, and wettability. As a consequence, significant enhancements of interfacial properties and hydrothermal aging resistance of composites were achieved, and interfacial reinforcing mechanisms have also been studied. Moreover, the storage modulus showed a 17.95% improvement, and the glass transition temperature was enhanced by 17 degrees C by dynamic mechanical analysis testing.
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