4.5 Article

Investigation of Co-Gasification Reactivity of Torrefied Jatropha Seed Cake with Illinois #6 Coal Char

期刊

BIORESOURCES
卷 11, 期 3, 页码 7624-7636

出版社

NORTH CAROLINA STATE UNIV DEPT WOOD & PAPER SCI
DOI: 10.15376/biores.11.3.7624-7636

关键词

Jatropha seed cake; Torrefaction; IL #6 coal char; Co-gasification; Reactivity

资金

  1. National Youth Science Foundation of China [21206104, 51406129]
  2. National Natural Science Foundation of China [21376158]

向作者/读者索取更多资源

Coal and torrefied biomass co-gasification is one of the potential solutions to the reduction of greenhouse gas emissions. For this study, Jatropha seed cake was torrefied at a temperature range of 200 to 300 degrees C under a nitrogen atmosphere. The torrefied material was then co-pyrolyzed and isothermally co-gasified at 900 degrees C with two Illinois (IL) #6 coal chars in a fixed-bed reactor connected to an on-line gas chromatography analyzer. Carbon dioxide and carbon monoxide were the primary gas products from the torrefaction process. Kinetic models, such as the shrinking core model, the homogenous model, and the catalysis-controlled model, were used to analyze the gasification mechanism. The results showed that the shrinking core and homogenous models provided the best fits for the gasification reaction data. Jatropha seed cake torrefied at 260 and 280 degrees C exhibited the best reaction activity with the IL #6 coal chars. The reactivities of coal char with torrefied biomass obtained at 200 and 300 degrees C were lower in comparison with the others.

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