期刊
PETROLEUM CHEMISTRY
卷 59, 期 11, 页码 1201-1206出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0965544119110124
关键词
asphaltene; adsorption; equilibrium; nanoparticles; surface chemistry; thermodynamics
This study investigates the equilibrium adsorption of asphaltene onto several nanoparticles (NiO, MgO, Fe3O4) with different surface chemistry at various temperatures by UV-Vis spectroscopy. The NiO had acidic surface; however the MgO and Fe3O4 had basic and amphoteric surfaces respectively, which were determined by titration method. The isotherm data of the nanoparticles were best modeled by Langmuir model that indicated monolayer asphaltene adsorption onto the nanoparticles. The maximum asphaltene adsorption capacities of the nanoparticles were obtained at minimum temperature (25 degrees C) in the range of 0.6364-1.0545 mg/m(2) that decreased in the order of NiO > MgO > Fe3O4. The results confirm the potential application of nanoparticles with acidic surface for adsorption and removing of asphaltene. Moreover, the thermodynamic parameters at different temperatures showed that the adsorption of asphaltene onto the nanoparticles was spontaneous (Delta G(0) < 0), exothermic (Delta H-0 < 0) and physical (2.1< |Delta H-0| <20.9 kJ/mol).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据