期刊
BIORESOURCE TECHNOLOGY
卷 220, 期 -, 页码 168-174出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2016.08.071
关键词
Digestate; Hydrothermal carbonization; Biochar; Pyrolysis; Surface area; PAH
资金
- German Federal Ministry of Education and Research (BMBF) [03SF0381A]
- Ohio University
Digestate from anaerobic digestion of biomass often contains more than 90% of water, which is economically unfavorable for pyrolysis. Hydrothermal carbonization (HTC) has potential to treat very wet biomass, however, the hydrochar may be acidic, contains polycyclic aromatic hydrocarbons (PAH) and toxic organic substances (e.g., phenolic compounds), and has very low Brunauer-Emmett-Teller (BET) surface area. In this study, pyrolysis of digestate derived hydrochar is performed at various pyrolysis and HTC temperatures. Solid chars were characterized for elemental analysis, pH, PAH, BET, pore size and volume, and phenolic substances, while HTC process liquids were characterized for pH, organic acids, furfural derivatives, and phenolic substances. Physicochemical characteristics of pyro-HTC char were compared with corresponding pyrochar and hydrochar. Pyro-HTC chars produced at higher HTC (i.e., 260 degrees C) and pyrolysis temperatures (i.e., 800 degrees C) showed highest BET surface area (63.5 m(2) g (1)), no PAH, relatively mild basic pH (9.34), and no phenolic compounds. (C) 2016 Elsevier Ltd. All rights reserved.
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