期刊
BIORESOURCE TECHNOLOGY
卷 220, 期 -, 页码 414-424出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2016.08.016
关键词
Microbial degradation; Laccase; Industrial lignin; Thermal carbon analysis; TD-pyrolysis-GC-MS
资金
- National Science Foundation Research [IIA-1330840]
- Office Of The Director
- Office of Integrative Activities [1330840] Funding Source: National Science Foundation
Indulin AT biodegradation by basidiomycetous fungi, actinobacteria and commercial laccases was evaluated using a suite of chemical analysis methods. The extent of microbial degradation was confirmed by novel thermal carbon analysis (TCA), as the treatments altered the carbon desorption and pyrolysis temperature profiles in supernatants. Laccase treatments caused only minor changes, though with increases occurring in the 850 degrees C and char precursor fractions. After fungal treatments, lignin showed a similar change in the TCA profile, along with a gradual decrease of the total carbon, signifying lignin mineralization (combined with polymerization). By contrast, bacteria produced phenolic monomers without their further catabolism. After 54 days of cultivation, a 20 wt% weight loss was observed only for fungi, Coriolus versicolor, corroborating the near-80% carbon mass balance closure obtained by TCA. Compositional changes in lignin as a result of biodegradation were confirmed by thermal desorption (TD)-pyrolysis-GC-MS validating the carbon fractionation obtained by TCA. (C) 2016 Elsevier Ltd. All rights reserved.
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