期刊
ORGANIC LETTERS
卷 21, 期 23, 页码 9550-9554出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b03722
关键词
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资金
- National Natural Science Foundation of China [21871178, 21702135]
- Innovation Fund from Joint Research Center for Precision Medicine by Shanghai Jiao Tong University AMP
- Affiliated Sixth People's Hospital South Campus [IFPM2017B009]
An electrophilic thiocyano semipinacol rearrangement of allylic alcohols has been achieved for the first time by using N-thiocyano-dibenzenesulfonimide (NTSI). This approach provides a direct, simple, and efficient strategy for the formation of thiocyano carbonyl compounds with moderate to excellent yields. Meanwhile, an all-carbon quaternary center was rapidly constructed. In addition, an asymmetric version of this tandem reaction was preliminarily investigated.
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