期刊
ORGANIC LETTERS
卷 21, 期 22, 页码 9045-9049出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b03443
关键词
-
资金
- Natural Science Foundation of China [21871179, 21572130]
- Shanghai Jiao Tong University
A useful method for the enantioselective preparation of isoxazoline N-oxides via Pd-catalyzed asymmetric allylic cycloaddition of nitro-containing allylic carbonates has been developed. By using palladium complex in situ generated from Pd-2(dba)(3)center dot CHCl3 and phosphoramidite L2 as a catalyst under mild conditions, the transformation afforded vinylated isoxazoline N-oxides in high yields with acceptably high enantioselectivities.
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