期刊
ORGANIC LETTERS
卷 21, 期 22, 页码 9014-9018出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b03417
关键词
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资金
- National Natural Science Foundation of China [21403154]
- Natural Science Foundation of Tianjin [13JCYBJC38700]
- Tianjin Municipal Education Commission [2018KJ137]
- 131 Talents Program of Tianjin and Training Project of Innovation Team of Colleges and Universities in Tianjin [TD13-5020]
Eight-membered cyclic and [5,5]-bicyclic sulfides were synthesized via a domino reaction between thioaurone analogues and arynes. Density functional theory calculations were performed to elucidate the reaction mechanism, which involves the elementary steps of the [3 + 2] cycloaddition, 1,2-hydrogen shift, and C(sp(2))-S bond cleavage as well as the substituent effect.
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