期刊
ORGANIC LETTERS
卷 21, 期 22, 页码 9066-9070出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b03460
关键词
-
资金
- NSFC [31630004, 41911530078]
- MOST [2018YFC1406705]
- Chinese Academy of Sciences [QYZDJ-SSW-DQC004]
Two polyketides neoenterocins A (1) and B (2), featuring a neighboring dicarbonyl motif and a furan-containing 5/6 ring system, were isolated from the enterocin producer Streptomyces sp. SCSIO 11863. Heterologous expression, gene disruptions, and isotope feeding experiments indicated that 1 and 2 were derived from the enterocin biosynthetic gene cluster. However, 2 was demonstrated as an artifact from enterocin via a unique skeleton rearrangement.
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