期刊
ORGANIC LETTERS
卷 21, 期 21, 页码 8722-8725出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b03337
关键词
-
资金
- National Natural Science Foundation of China [21801198]
- Wuhan Institute of Technology [17QD05]
The intrinsic electrophilic feature for the terminal nitrogen of alpha-diazo-beta-ketoesters/ketones has been elucidated by the intermolecular nucleophilic addition of two molecules of a dimethylsulfonium ylide. This methodology allows for access to highly functionalized hydrazones with a broad scope and good functional group tolerance. The reaction operates under simple and mild conditions without using a catalyst.
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