4.6 Article

Effects of CsPbBr3 nanocrystals concentration on electronic structure and surface composition of perovskite films

期刊

ORGANIC ELECTRONICS
卷 73, 期 -, 页码 327-331

出版社

ELSEVIER
DOI: 10.1016/j.orgel.2019.06.040

关键词

CsPbBr3 NCs; Perovskite films; Electronic structure; Photoemission spectroscopy

资金

  1. National Key Research and Development Program of China [2017YFA0206602]
  2. National Natural Science Foundation of China [11334014, 51802355]
  3. National Key Laboratory Open Project Foundation [165000001]
  4. Natural Science Foundation of Hunan Province [2018JJ3625]
  5. Innovation Fund for Graduate Students of CSU [2018zzts349]
  6. National Science Foundation [DMR-1903981, 1903962]
  7. Direct For Mathematical & Physical Scien
  8. Division Of Materials Research [1903962] Funding Source: National Science Foundation

向作者/读者索取更多资源

The electronic structure and surface composition of perovskite films after incorporation of different concentration of CsPbBr3 nanocrystals (NCs) have been investigated with ultraviolet photoelectron spectroscopy (UPS) and X-ray, and angle-resolved photoelectron spectroscopy (XPS, AR-XPS). The electronic structure, surface composition and morphology of perovskite film have been changed through the interaction between CsPbBr3 NCs and perovskite film. The band can be shifted upward by in incorporation of CsPbBr3 NCs and it is independent of the concentration of CsPbBr3 NCs. The surface component and its distribution can be adjusted by changing the concentration of CsPbBr3 NCs and the proper concentration of CsPbBr3 NCs would improve the stoichiometric ratio of perovskite film.

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