期刊
BIORESOURCE TECHNOLOGY
卷 212, 期 -, 页码 302-310出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2016.04.029
关键词
Kraft lignin; Isopropanol; Hydrocracking; Orthogonal array design; Nobel metal catalysts
资金
- Shanghai Science and Technology Committee [14231200300]
Catalytic hydrocracking of kraft lignin was carried out in isopropanol system and an orthogonal array design (OAD) was employed to optimize the experimental conditions. GC-MS/FID, elemental analysis, GPC and H-1-C-13 HSQC NMR were carried out for entire investigation of the liquid products. The results indicated that the hydrocracking process was thermally controlled and catalysts showed significant influences on the product distributions. Comparing with Pd/C, Pt/C and Ru/C, Rh/C inhibited the self condensation of isopropanol and reduced the formation of oxygenic-chain compounds. The excellent catalytic activity for phenols conversion was obtained over Rh/C. The routes of oxygenic-chain compounds formation and phenol conversion were proposed in detail. The least oxygenic-chain compounds formation, the highest phenols conversion (93.4%), the lowest O/C ratio (0.094) and the highest HHV (37.969 MJ/kg) provided the possibility of the high quality bio-oil obtained over Rh/C in isopropanol medium. (C) 2016 Elsevier Ltd. All rights reserved.
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