Synthesis of citric acid functionalized magnetic graphene oxide coated corn straw for methylene blue adsorption

The citric acid functionalized magnetic graphene oxide coated corn straw (CA-mGOCS) as a new adsorbent was synthesized in this work for the elimination of methylene blue (MB) from waste water. The as-prepared CA-mGOCS was tested by SEM, FTIR, XRD, Roman spectrum, TGA, particle size analyzer, BET and magnetic properties analyzer. Some factors affecting adsorption removal efficiency were explored. As a result, the addition of 5 g CS (CA-mGO5CS) had the better adsorption performance than other adsorbents. The pseudo-second-order model and the Freundlich described the adsorption behavior well. The equilibrium adsorption capacity was 315.5 mg g(-1) for MB at pH = 12 and 298 k. The electrostatic incorporation as well as hydrophobic interactions between CA-mGO5CS and MB determined the favourable adsorption property. Besides, the thermodynamic studies results Delta G < 0, Delta H < 0, Delta S < 0 suggested that the adsorption was a spontaneous, exothermic and randomness decrease process. Finally, reusability studies imply that CA-mGO5CS has an excellent reproducibility. (C) 2016 Elsevier Ltd. All rights reserved.